Borane

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Borane


Borane is a chemical compound consisting of boron and hydrogen with the general formula BxHy. These compounds do not exist as a single entity but form a series of compounds that include monoborane (BH), diborane (B2H6), and higher boranes such as tetraborane (B4H10), pentaborane (B5H9), and decaborane (B10H14). Among these, diborane is the most extensively studied and widely used compound.

Boranes are characterized by their electron-deficient nature, making them useful as reagents in organic chemistry for hydroboration reactions. Hydroboration is a process where boranes add across the carbon-carbon double bond of alkenes to give trialkylboranes, which are important intermediates in organic synthesis, particularly in the conversion to alcohols or other functional groups through subsequent reactions.

The synthesis of boranes typically involves the reduction of boron halides with hydrogen or metal hydrides. Diborane, for example, can be produced through the reaction of boron trifluoride (BF3) with sodium hydride (NaH).

Boranes are also of interest in the field of materials science for their potential use in hydrogen storage materials due to their high hydrogen content. However, their practical application is limited by issues such as toxicity and flammability, particularly for the smaller boranes like diborane.

In addition to their use in organic synthesis and potential applications in materials science, boranes have been studied for their use as rocket fuels, given their high energy content. However, the handling difficulties and safety concerns associated with their high reactivity and toxicity have limited their practical applications in this area.

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Contributors: Prab R. Tumpati, MD