Vanadium pentafluoride

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Vanadium pentafluoride is a chemical compound with the formula VF5. It is one of the higher fluorides of vanadium, a transition metal, and is notable for its uncommon oxidation state of +5. Vanadium pentafluoride is part of a family of vanadium fluorides that include VF2, VF3, and VF4, each exhibiting different properties and applications due to the varying oxidation states of vanadium.

Properties[edit | edit source]

Vanadium pentafluoride is a volatile, colorless to pale yellow liquid at room temperature, making it distinct from the solid states of its lower fluoride counterparts. It has a strong oxidizing property and reacts violently with water, releasing oxygen and forming vanadium(V) oxide and hydrofluoric acid. Due to its high reactivity, VF5 is usually handled under strict safety protocols to prevent its decomposition and the subsequent release of toxic gases.

Synthesis[edit | edit source]

The synthesis of vanadium pentafluoride typically involves the direct fluorination of vanadium metal or vanadium(V) oxide with elemental fluorine. The reaction requires careful control of temperature and the use of corrosion-resistant equipment due to the aggressive nature of fluorine gas and the product itself.

Applications[edit | edit source]

Vanadium pentafluoride is primarily used in research settings, particularly in the study of its potential as a catalyst in certain organic reactions. Its strong oxidizing ability can be harnessed to facilitate the breakdown of complex organic molecules, although its practical applications are limited by its reactivity and the difficulty in handling.

Safety[edit | edit source]

Handling vanadium pentafluoride requires stringent safety measures due to its corrosive nature and the potential release of toxic gases upon decomposition. Appropriate personal protective equipment (PPE), such as gloves and goggles, and the use of fume hoods are essential when working with this compound.

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Contributors: Prab R. Tumpati, MD